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Zusammenfassung Bei dem Versuch, die Kristallstruktur von Bonchevit zu bestimmen, stellte sich heraus, daß dieses Mineral—bis dahin PbBi4S7—aus zwei Phasen besteht. Der Hauptanteil wurde eindeutig als Galenobismutit identifiziert. Der Rest wies nach den Gitterkonstanten (a0=13,58±0,02 Å, b0=20,51±0,07 Å, c0=4,09±0,07 Å) auf ein bisher unbekanntes Mineral hin. Die Raumgruppe ist Bbmm. Ein indiziertes Pulverdiagramm und die dazugehörigen d-Werte werden angegeben.Die Emissionsspektralanalyse zeigt Pb und Bi als Hauptkomponenten, Cu und Ag als Nebenkomponenten und Spuren von Zn und Sn. Die Strukturanalyse führte zu der Formel Me5S6, wobei die Me-Atome etwa gleich schwer sind, so daß als chemischo Formel nur Pb3Bi2S6 mit Z=4 in Frage kommt.Strukturell gehört das Mineral in die Gruppe Andorit-Ramdohrit-Fizelyit. Die Verwandtschaft bzw. Identität des Minerals mit anderen Mineralen und synthetischen Verbindungen wird diskutiert.
Mineralogical data on a sulphosalt from the Rhodope mountains, Bulgaria
Summary During an attempt to determine the crystal structure of bonchevite, this mineral was found to consist of two phases. Previously it was thought to have the composition PbBi4S7. The main constituent could unambiguously be identified as galenobismutite. For the rest the lattice constants (a0=13.58±0,02 Å, b0=20.51±0,07 Å, c0=4.09±0.07 Å), indicated a new mineral. Space group is Bbmm. An indexed powder diagram (with d-values) is given.The emission spectrographic analysis shows Pb and Bi to be main components, Cu and Ag to be minor components, and traces only of Zn and Sn. The structure analysis has led to the formula Me5S6, with Me-atoms of approximately the same atomic number; therefore, the chemical formula has to be Pb3Bi2S6, with Z=4.In a structural classification the mineral belongs to the andoriteramdohrite-fizelyite-group. The relationships to or the identity with other minerals and synthetic compounds are discussed.
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The natural distribution of 36Cl/Cl in groundwater across the continental United States has recently been reported by Davis et al. (2003). In this paper, the large-scale processes and atmospheric sources of 36Cl and chloride responsible for controlling the observed 36Cl/Cl distribution are discussed.The dominant process that affects 36Cl/Cl in meteoric groundwater at the continental scale is the fallout of stable chloride from the atmosphere, which is mainly derived from oceanic sources. Atmospheric circulation transports marine chloride to the continental interior, where distance from the coast, topography, and wind patterns define the chloride distribution. The only major deviation from this pattern is observed in northern Utah and southern Idaho where it is inferred that a continental source of chloride exists in the Bonneville Salt Flats, Utah.In contrast to previous studies, the atmospheric flux of 36Cl to the land surface was found to be approximately constant over the United States, without a strong correlation between local 36Cl fallout and annual precipitation. However, the correlation between these variables was significantly improved (R 2=0.15 to R 2=0.55) when data from the southeastern USA, which presumably have lower than average atmospheric 36Cl concentrations, were excluded. The total mean flux of 36Cl over the continental United States and total global mean flux of 36Cl are calculated to be 30.5±7.0 and 19.6±4.5 atoms m–2 s–1, respectively.The 36Cl/Cl distribution calculated by Bentley et al. (1986) underestimates the magnitude and variability observed for the measured 36Cl/Cl distribution across the continental United States. The model proposed by Hainsworth (1994) provides the best overall fit to the observed 36Cl/Cl distribution in this study. A process-oriented model by Phillips (2000) generally overestimates 36Cl/Cl in most parts of the country and has several significant local departures from the empirical data.
Resumen Davis et al. (2003) han informado de la distribución natural de la proporción 36Cl/Cl en las aguas subterráneas de la parte continental de los Estados Unidos de América [EUA]. En este artículo, se discute cuáles son los procesos a gran escala y las fuentes atmosféricas del 36Cl y del cloruro que dan lugar a la distribución observada de 36Cl/Cl.El proceso dominante que afecta a la relación 36Cl/Cl en las aguas subterráneas de origen meteórico a escala continental es el aporte de cloruro estable desde la atmósfera, que procede principalmente de los océanos. La circulación atmosférica transporta el cloruro marino hacia el interior, donde la distancia a la costa, topografía y corrientes del viento definen la distribución del cloruro. La única desviación principal de este esquema tiene lugar al norte de Utah y en el sur de Idaho, donde se deduce que existe una fuente continental de cloruro en los Rellanos Salados de Bonneville (Salt Flats).En contraste con estudios previos (Knies et al. 1994; Phillips 2000), se ha descubierto que el flujo atmosférico de 36Cl hacia la superficie terrestre es aproximadamente constante en todos los estados, sin deducirse una correlación fuerte entre el aporte de 36Cl y la precipitación anual. Sin embargo, la correlación entre estas variables se ve mejorada de forma significativa, con coeficientes de regresión comprendidos entre 0,15 y 0,55, cuando se excluyen los datos recogidos en el sudeste de los EUA, que tienen concentraciones de 36Cl atmosférico presuntamente inferiores a la media. El flujo medio total de 36Cl calculado en la zona continental de los Estados Unidos vale 30,5±7,0 átomos por metro cuadrado y segundo, mientras que el flujo total global de 36Cl es de 19,6±4,5 átomos por metro cuadrado y segundo.La distribución de 36Cl/Cl calculada por Bentley et al. (1986) infravalora la magnitud y variabilidad observada en los valores medidos a lo largo de los Estados Unidos. El modelo propuesto por Hainsworth (1994) proporciona el mejor ajuste conjunto a la distribución observada de 36Cl/Cl en este estudio. El modelo orientado a procesos de Phillips (2000) sobreestima por lo general la distribución de 36Cl/Cl en la mayoría del país y difiere significativamente de algunos valores locales empíricos.

Résumé La distribution naturelle du rapport 36Cl/Cl dans les eaux souterraines des États-Unis a été récemment présentée par Davis et al. (2003). Dans ce travail, les processus à grande échelle et les sources atmosphériques de 36Cl et de chlorure responsables du contrôle de la distribution observée du rapport 36Cl/Cl sont discutés. Le processus dominant qui affecte le rapport 36Cl/Cl dans les eaux souterraines dorigine météorique à léchelle continentale est lapport atmosphérique de chlorure stable, qui provient pour lessentiel de sources océaniques. La circulation atmosphérique transporte des chlorures marins vers lintérieur des continents, où la distribution de chlorure est définie par la distance à la côte, la topographie et les régimes des vents. La seule exception majeure à ce schéma est observée dans le nord de lUtah et le sud de lIdaho où lon suppose quil existe une source continentale de chlorure dans les bas-fonds salés de Bonneville. Au contraire de précédentes études (Knies et al. 1994; Phillips 2000), on trouve que le flux atmosphérique de 36Cl vers le sol est approximativement constant sur lensemble des États-Unis, sans forte corrélation entre la retombée locale de 36Cl et les précipitations annuelles. Cependant, la corrélation entre ces variables devient significative (R 2=0.15 à 0.55) lorsquon supprime les données du sud-est des États-Unis, dont on pense quelles présentent des concentrations en 36Cl atmosphérique inférieures à la moyenne. Le flux total moyen de 36Cl sur les États-Unis continentaux et le flux moyen global de 36Cl sont respectivement évalués à 30.5 ± 7.0 et 19.6 ± 4.5 atomes.m–2.s–1. La distribution du rapport 36Cl/Cl calculée par Bentley et al. (1986) sous-estime lordre de grandeur et la variabilité observés pour la distribution mesurée du rapport 36Cl/Cl sur les États-Unis continentaux. Le modèle proposé par Hainsworth (1994) fournit le meilleur ajustement densemble à la distribution du rapport 36Cl/Cl observée dans cette étude. Un modèle orienté vers les processus proposé par Phillips (2000) surestime dans lensemble le rapport 36Cl/Cl dans la plupart des régions du pays et présente plusieurs désaccords locaux avec les données empiriques.
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Tornadoes have occurred in the territory of the Czech Republic throughout history. Although their frequency and intensity are not as high as in the USA, they can cause severe damage as well. That is why a systematic effort to document individual occurrences of this dangerous meteorological phenomenon as far as possible back into the past began in the 1990s. The aim of this investigation is to extend the first European catalogue of tornadoes originally published by Wegener [Wegener A., 1917. Wind-und Wasserhosen in Europe], by the addition of these cases from the Czech Republic.This paper adds further to Setvák, Šálek and Munzar [Setvák M., Šálek M., Munzar J., 2003. Tornadoes within the Czech Republic—from medieval chronicles to the internet society. Atmos. Res. 67–68, 589–605], who reported the earliest documented tornado in the land of the Czech Republic which occurred in AD 1119 in Prague. In so doing, it presents recently discovered tornado cases from the 16th to the early 20th centuries, found in a variety of historical sources since the last ECSS conference held in Prague in 2002. In particular we will focus on the case from Jablonec nad Nisou (northern Bohemia) in 1925, which was probably the first case in the Czech Republic with accompanying photographic documentation of damage caused by a tornado.  相似文献   
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This paper is devoted to the testing experiment of a postprocessing tool aimed at the objective analysis of propagating gust fronts in a given convective environment. The tool is being developed to be applicable in the operational mode by utilizing NWP model outputs. The experiment was carried out on two summer convective cases which occurred in the Czech Republic. The cases were numerically simulated by the limited area NWP model LM COSMO with the horizontal resolution of 2.8 km. They represent different types of convective systems, both accompanied by objectively identifiable gust fronts and causing heavy precipitation. The event from July 2000 was characterised by the development of isolated thunderstorms. The other event from July 1998 was a long-lasting and organised convective system — a squall line. The hypothesis was that the developed postprocessing tool is capable to evaluate the role which downdraft outflows played in the decay and initiation of convective cells by interaction with convective environment and thus in prolongation of convection lifetime.The procedures of the Objective Analysis of Gust Fronts (OAGF) were applied to the thermodynamic outputs of the LM COSMO. The aim was to determine the position of gust fronts within the domain and to assess their speed of movement and the potential to initiate convection according to the properties of ambient vertical shear and stability as well as humidity conditions ahead of the respective downdraft outflows. In addition, the Radar Simulation Model (RSM) was employed to monitor the simulated convective systems in arbitrary PPI and RHI scans and to verify qualitatively the LM COSMO precipitation forecasts.The case studies has confirmed the applicability of the LM COSMO–OAGF chain and RSM, which may represent the potential for improving the operational nowcasting of hazardous convection phenomena. In both simulations, the objective gust fronts moved on into the vertical shear-favourable environment for triggering new convection. In addition to the dynamical organisation, there were also favourable stability and humidity conditions in the area of forced upward motions in the simulation of the event from July 2000.  相似文献   
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The SUDETES 2003 wide-angle refraction/reflection experiment covered the area of the south-western Poland and the northern Bohemian Massif. The good quality data that were gathered combined with the data from previous experiments (POLONAISE'97, CELEBRATION 2000) allowed us to prepare a 3D seismic model of the crust and uppermost mantle for this area. We inverted travel times of both refracted and reflected P waves using the JIVE3D package. This allowed us to obtain a model of P-wave velocity distribution as well as the shape of major boundaries in the crust. We also present a detailed uncertainty analysis for both the boundary depths and the velocity field. In doing the uncertainty analysis we found an interesting, strong dependence between uncertainty and inversion scheme (order of used phases). We also compared the model with surface geology and found good correlation between velocity inhomogeneities in the uppermost crust (down to 2 km) and major geological units. The higher velocity lower crust (6.9–7.2 km/s) could result from remelting of the lower crust or magmatic underplating.  相似文献   
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Due to the social and economic implications, flood frequency analysis must be done with the highest precision. For this reason, the most suitable statistical model must be selected, and the maximum amount of information must be used. Floods in Mediterranean rivers can be produced by two different mechanisms, which forces the use of a non-traditional distribution like the TCEV. The information can be increased by using additional non-systematic data, or with a regional analysis, or both. Through the statistical gain concept, it has been shown that in most cases the use of additional non-systematic information can decrease the quantile estimation error in about 50%. In a regional analysis, the␣benefit of additional information in one station, is propagated to the rest of␣the␣stations with only a small decrease with respect to the at-site equivalent analysis.  相似文献   
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Although radio-quiet quasars (RQQs) constitute ≳ 90 per cent of optically identified quasar samples, their radio properties are only poorly understood. In this paper we present the results of a multi-frequency VLA study of 27 low-redshift RQQs. We detect radio emission from 20 objects, half of which are unresolved (≤ 0.24 arcsec). In cases where significant structure can be resolved, double, triple and linear radio sources on scales of a few kpc are found. The radio emission (typically) has a steep spectrum (α ∼ 0.7, where S  ∝ ν−α), and high brightness temperatures ( T B ≥ 105 K) are measured in some of the radio components. The RQQs form a natural extension to the radio luminosity–absolute magnitude distribution of nearby Seyfert 1s. We conclude that a significant fraction of the radio emission in RQQs originates in a compact nuclear source directly associated with the quasar. There are no significant differences between the radio properties of RQQs with elliptical hosts and those in disc galaxies within the current sample.  相似文献   
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